Chess Rules - Special Moves: En Passant
En Passant is a simple, but often confused rule.
The En Passant rule applies when a player moves a pawn 2 squares forward from it's initial position, and an opposing pawn could have captured it if it had only moved one square. In the turn immediately after this occurs (and only this turn) the opposing player may capture the pawn as if it had only moved 1 square.
The best way to understand the rule is to study the diagrams below: